Course Overview
You will be able to:
- Measure corrosion potentials and currents accurately.
- Build and interpret polarization curves.
- Determine corrosion rates from Tafel slopes.
- Diagnose passivation and activation behaviour.
Curriculum
Electrochemical Nature of Aqueous Corrosion
- Electrochemical nature of corrosion
- Corrosion classification & course focus
- Anodic & cathodic reactions
- Charge movement in metals & electrolytes
- Faraday’s law & calculation example
Corrosion Thermodynamics
- Pourbaix diagram of water
- Standard potentials & reference electrodes
- Electrochemical series
- Nernst equation
- Pourbaix diagrams of metals (Part 1 & 2)
Kinetics of Corrosion Reactions
- Reaction rates to electrical currents
- Current–potential diagrams & exchange current
- Activation‑controlled reactions – Butler–Volmer & Tafel
- Diffusion‑controlled cathodic reaction
- Hydrogen evolution
- Passivity
Corrosion Behaviours
- Evans diagrams
- Estimating corrosion currents (Stern–Geary)
- Galvanic effects & diffusion‑limited corrosion
- Passive metals behaviour
Electrochemical Measurements
- Three‑electrode cell setup
- Potential conversion to SHE
- Potentiodynamic vs linear polarization parameters
- Impact of electrolyte resistance